The vibrational relaxation of NO in Ar: tunneling in a curve-crossing mechanism
Author:
Affiliation:
1. Schulich Faculty of Chemistry
2. Technion – Israel Institute of Technology Haifa
3. Israel
4. Max-Planck-Institut für Biophysikalische Chemie
5. Göttingen D-37077
6. Germany
7. Institut für Physikalische Chemie
8. Universität Göttingen
Abstract
A qualitative reaction-coordinate picture of the nonadiabatic tunneling vibronic relaxation NO(X2Π, v = 1) + Ar → NO(X2Π, v = 0) + Ar at low temperatures.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP04107K
Reference32 articles.
1. Theory of non-adiabatic vibrational relaxation in atom-molecular collisions
2. E. E. Nikitin , Theory of Elementary Atomic and Molecular Processes in Gases, Oxford, Clarendon Press, 1974
3. Effect of vibronic interaction upon the vibrational relaxation of diatomic molecules
4. Mechanism of vibrational relaxation of NO upon collisions with Ar
5. Shock‐Tube Study of the Vibrational Relaxation of Nitric Oxide
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2. Electronically nonadiabatic mechanism of the vibrational relaxation of NO in Ar: Rate coefficients fromab initiopotentials and asymptotic coupling;The Journal of Chemical Physics;2018-07-07
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