Controlling the stereoselectivity of rac-LA polymerization by chiral recognition induced the formation of homochiral dimeric metal alkoxides-Reference-Cited by-同舟云学术

Controlling the stereoselectivity of rac-LA polymerization by chiral recognition induced the formation of homochiral dimeric metal alkoxides

Published:2016 Issue:11 Volume:7 Page:2022-2036
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Horeglad P.¹²³⁴,Cybularczyk M.¹²³⁴⁵,Litwińska A.⁵²⁶⁴,Dąbrowska A. M.¹²³⁴⁵,Dranka M.⁵⁷⁸⁴,Żukowska G. Z.⁵⁷⁸⁴,Urbańczyk M.¹²³⁴⁵,Michalak M.⁹¹⁰¹¹⁴

Affiliation:

1. Centre of New Technologies

2. University of Warsaw

3. 02-097 Warsaw

4. Poland

5. Faculty of Chemistry

6. 02-093 Warsaw

7. Warsaw University of Technology

8. Warsaw

9. Institute of Organic Chemistry

10. Polish Academy of Science

11. 01-224 Warsaw

Abstract

Chiral recognition of monomeric Me₂MOR units resulting in the formation of homochiral dimeric species [Me₂M(μ-OR)]₂(M = Ga, In), leads to heteroselective catalysts for the ring opening polymerization ofrac-lactide (rac-LA).

Funder

Narodowe Centrum Nauki

Ministerstwo Nauki i Szkolnictwa Wyzszego

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2016/PY/C5PY02005K

Reference122 articles.

1. Nonlinear effects in asymmetric synthesis. Examples in asymmetric oxidations and aldolization reactions

2. Nonlinear Effects in Asymmetric Catalysis

3. Nonlinear Effects in Asymmetric Synthesis and Stereoselective Reactions: Ten Years of Investigation

4. Absolute Asymmetric Synthesis: The Origin, Control, and Amplification of Chirality

5. Practical Consequences of Non-Linear Effects in Asymmetric Synthesis

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