Synthesis of 1,3-disubstituted cyclohexenes from dienylethers via sequential hydrozirconation/deoxygenative cyclisation-Reference-Cited by-同舟云学术

Synthesis of 1,3-disubstituted cyclohexenes from dienylethers via sequential hydrozirconation/deoxygenative cyclisation

Published:2019 Issue:4 Volume:17 Page:798-802
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Payet Amandine¹²³⁴,Blondeau Benjamin¹²³⁴,Behr Jean-Bernard¹²³⁴^ORCID,Vasse Jean-Luc¹²³⁴^ORCID

Affiliation:

1. Institut de Chimie Moléculaire de Reims

2. CNRS (UMR 7312) and Université de Reims Champagne Ardenne

3. 51687 Reims Cedex 2

4. France

Abstract

The preparation of 1,3-disubstituted cyclohexenes from 3-methoxyhexa-1,5-dienes involving a sequential hydrozirconation/TMSOTf-mediated activation is described.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C8OB02925C

Reference49 articles.

1. ω-Ethylenic Allylic Substrates as Alternatives to Cyclic Substrates in Copper- and Iridium-Catalyzed Asymmetric Allylic Alkylation

2. Coordinatively unsaturated ruthenium allenylidene complexes: highly effective, well defined catalysts for the ring-closure metathesis of α,ω-dienes and dienynes

3. The direct arylation of allylic sp3 C–H bonds via organic and photoredox catalysis

4. Hexafluoroisopropanol-Promoted Metal-Free Allylation of Silyl Enol Ethers with Allylic Alcohols

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