Formation of the acenaphthylene cation as a common C<sub>2</sub>H<sub>2</sub>-loss fragment in dissociative ionization of the PAH isomers anthracene and phenanthrene-Reference-Cited by-同舟云学术

Formation of the acenaphthylene cation as a common C₂H₂-loss fragment in dissociative ionization of the PAH isomers anthracene and phenanthrene

Published:2022 Issue:44 Volume:24 Page:27343-27354
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Banhatti Shreyak¹,Rap Daniël B.²^ORCID,Simon Aude³^ORCID,Leboucher Heloïse³^ORCID,Wenzel Gabi⁴,Joblin Christine⁵^ORCID,Redlich Britta²,Schlemmer Stephan¹^ORCID,Brünken Sandra²^ORCID

Affiliation:

1. I. Physikalisches Institut, Universität zu Köln, Zülpicher Str. 77, 50937 Köln, Germany

2. Institute for Molecules and Materials, FELIX Laboratory, Radboud University, Toernooiveld 7, 6525 ED, Nijmegen, The Netherlands

3. Laboratoire de Chimie et Physique Quantiques (LCPQ), Fédération FeRMI, CNRS & Université Toulouse III – Paul Sabatier, 118 Route de Narbonne, 31062 Toulouse, France

4. Center for Interstellar Catalysis (InterCat), Department of Physics and Astronomy, Aarhus University, Ny Munkegade 120, 8000 Aarhus C, Denmark

5. Institut de Recherche en Astrophysique et Planétologie (IRAP), Université Toulouse III – Paul Sabatier, CNRS, CNES, 9 Avenue du Colonel Roche, 31028 Toulouse, France

Abstract

This study uses cryogenic infrared spectroscopy combined with quantum-chemical and molecular dynamics calculations to elucidate the acetylene-loss fragmentation pathway in the dissociative ionization of two isomeric polycyclic aromatic hydrocarbons.

Funder

H2020 Marie Skłodowska-Curie Actions

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Deutsche Forschungsgemeinschaft

Seventh Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP03835H

Reference63 articles.