Unraveling the effects on lithium-ion cathode performance by cation doping M–Li2CuO2 solid solution samples (M = Mn, Fe and Ni)

Author:

Martínez-Cruz M. A.1234,Yañez-Aulestia A.56783ORCID,Ramos-Sánchez G.934,Oliver-Tolentino M.934ORCID,Vera M.1234ORCID,Pfeiffer H.56783,Ramírez-Rosales D.10114,González I.1234

Affiliation:

1. Universidad Autónoma Metropolitana-Iztapalapa

2. Departamento de Química

3. Ciudad de México

4. Mexico

5. Laboratorio de Fisicoquímica y Reactividad de Superficies (LaFReS)

6. Instituto de Investigaciones en Materiales

7. Universidad Nacional Autónoma de México

8. Ciudad Universitaria

9. CONACYT – Universidad Autónoma Metropolitana – Iztapalapa

10. Instituto Politecnico Nacional-ESFM

11. México City 07738

Abstract

Manganese partial substitution reveals a drastic improvement in the electrochemical stability of Li2CuO2 during the charge/discharge processes, this is attributed to the increase in the superexchange interaction between copper sites and manganese.

Funder

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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