Mesoionic carbene-based self-assembled monolayers on gold

Author:

Lee Dianne S.12ORCID,Singh Ishwar12ORCID,Veinot Alex J.234ORCID,Aloisio Mark D.12ORCID,Lomax Justin T.234ORCID,Ragogna Paul J.23ORCID,Crudden Cathleen M.12ORCID

Affiliation:

1. Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, Ontario, K7L 3N6, Canada

2. Carbon to Metal Coating Institute, C2MCI, Queen's University, 90 Bader Lane, Kingston, Ontario, K7L 4V1, Canada

3. Department of Chemistry, Western University, London, Ontario N6A 3K7, Canada

4. Surface Science Western, 999 Collip Cir, London, Ontario, N6G 0J3, Canada

Abstract

N-heterocyclic carbenes (NHCs) have been widely studied as ligands for surface chemistry, and have shown advantages compared to existing ligands (e.g. thiols). Herein, we introduce mesoionic carbenes (MICs) as a new type of surface ligand.

Funder

Queen's University

Canada Foundation for Innovation

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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