Alumina-mediated soft propargylic C–H activation in unactivated alkynes-Reference-Cited by-同舟云学术

Alumina-mediated soft propargylic C–H activation in unactivated alkynes

Published:2022 Issue:12 Volume:24 Page:4761-4765
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Feofanov Mikhail¹^ORCID,Sharapa Dmitry I.²^ORCID,Akhmetov Vladimir¹^ORCID

Affiliation:

1. Institute of Chemistry, Organic Chemistry, Martin-Luther-University Halle-Wittenberg, Kurt-Mothes-Strasse 2, D-06120 Halle, Germany

2. Institute of Catalysis Research and Technology, Karlsruhe Institute of Technology; Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany

Abstract

Pre-treated γ-alumina features reactive centers mimicking electronic interactions of propargyls with transition-metal-based catalysts. The combination of soft π-Lewis acidity and Brønsted basicity allows C-H propargyl activation under mild conditions.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/GC/D2GC00555G

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