Iron(iii) carboxylate/aminoalcohol coordination clusters with propeller-shaped Fe8 cores: approaching reasonable exchange energies-Reference-Cited by-同舟云学术

Iron(iii) carboxylate/aminoalcohol coordination clusters with propeller-shaped Fe8 cores: approaching reasonable exchange energies

Published:2015 Issue:47 Volume:44 Page:20753-20762
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Botezat Olga¹²³⁴⁵,van Leusen Jan⁵⁶⁷⁸,Ch. Kravtsov Victor¹²³⁴,Ellern Arkady⁹¹⁰¹¹¹²,Kögerler Paul⁵⁶⁷⁸,Baca Svetlana G.¹²³⁴

Affiliation:

1. Institute of Applied Physics

2. Academy of Science of Moldova

3. MD2028 Chisinau

4. R. Moldova

5. Institute of Inorganic Chemistry

6. RWTH Aachen University

7. 52074 Aachen

8. Germany

9. Department of Chemistry

10. Iowa State University

11. Ames

12. USA

Abstract

A new approach has been used to determine reasonable exchange energies in a series of new octanuclear propeller-shaped Fe(iii) clusters that feature distorted hexagonal-bipyramidal Fe₈ polytopes of isotropic spin-5/2 centers.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT03024B

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