Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands-Reference-Cited by-同舟云学术

Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands

Published:2020 Issue:28 Volume:49 Page:9583-9587
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sánchez Práxedes¹²³⁴^ORCID,Hernández-Juárez Martín⁵⁶⁷^ORCID,Rendón Nuria¹²³⁴^ORCID,López-Serrano Joaquín¹²³⁴^ORCID,Santos Laura L.¹²³⁴^ORCID,Álvarez Eleuterio¹²³⁴^ORCID,Paneque Margarita¹²³⁴^ORCID,Suárez Andrés¹²³⁴^ORCID

Affiliation:

1. Instituto de Investigaciones Químicas (IIQ)

2. Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA). CSIC and Universidad de Sevilla. Avda. Américo Vespucio 49

3. Sevilla

4. Spain

5. Centro de Investigaciones Químicas. Universidad Autónoma del Estado de Hidalgo. Km. 14.5 Carretera Pachuca-Tulancingo. C.P. 42184

6. Hidalgo

7. Mexico

Abstract

Ru-CNN(H) complexes are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Under basic conditions, these derivatives lead to the formation of Ru(0) species that are observed under catalytic conditions.

Funder

Ministerio de Ciencia e Innovación

Junta de Andalucía

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02326D

Reference32 articles.

1. The NH Functional Group in Organometallic Catalysis

2. Metal-Ligand Cooperation