Sequestration of carbon monoxide at room temperature at vacancy sites of graphene

Author:

Chiarello Gennaro1234,Fabio Vito1234,Boukhvalov Danil W.56789,Politano Antonio1011124ORCID

Affiliation:

1. Department of Physics

2. University of Calabria

3. 87036 Rende (CS)

4. Italy

5. College of Science

6. Institute of Materials Physics and Chemistry

7. Nanjing Forestry University

8. Nanjing 210037

9. P. R. China

10. Department of Physical and Chemical Sciences

11. University of L’Aquila

12. 67100 L’Aquila (AQ)

Abstract

Unsaturated C atoms at vacancies of the graphene lattice are able to capture carbon monoxide at room temperature, with the formation of C–O–C bonds, as indicated by their corresponding vibrational mode at 150 meV (1209 cm−1).

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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