Visible light induced 3-position-selective addition of arylpropiolic acids with ethers via C(sp3)–H functionalization
Author:
Affiliation:
1. School of Chemical Engineering
2. Nanjing University of Science and Technology
3. Nanjing 210094
4. China
Abstract
Although the 2-position-selective decarboxylative coupling or addition of arylpropiolic acids with cyclic ethers has been intensively investigated, selective functionalization of arylpropiolic acids at the 3-position is still a big challenge.
Funder
Qinglan Project of Jiangsu Province of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB00480D
Reference78 articles.
1. Recent advances of propiolic acids in organic reactions
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4. Rhodium-Catalyzed Enantioselective Decarboxylative Alkynylation of Allenes with Arylpropiolic Acids
5. Synthesis of 1,4-diarylsubstituted 1,3-diynes through ligand-free copper-catalyzed oxidative decarboxylative homocoupling of aryl propiolic acids
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1. Progress ofα-Position Functionalization of Ethers under Photo/Electrocatalysis;Chinese Journal of Organic Chemistry;2023
2. α-Csp3–H Bond Functionalization of Simple Ethers in Radical Reactions;Synthesis;2021-09-02
3. Decarboxylative Oxyacyloxylation of Propiolic Acids: Construction of Alkynyl-Containing α-Acyloxy Ketones;The Journal of Organic Chemistry;2021-06-04
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