Theoretical and experimental mechanistic study of water molecule involvement in the Prilezhaev reaction-Reference-Cited by-同舟云学术

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Theoretical and experimental mechanistic study of water molecule involvement in the Prilezhaev reaction

Published:2023 Issue:27 Volume:25 Page:18102-18108
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kawahara Eri Maeyama¹^ORCID,Ogawa Mitsuhiro¹,Yamato Shiho¹,Yamaguchi Toru²,Hori Kenji¹²,Sumimoto Michinori¹^ORCID

Affiliation:

1. Division of Materials Science, Graduate School of Science and Technology for Innovation, Yamaguchi, 7558611, Japan

2. Transition State Technology Company Limited, 7558611, Japan

Abstract

Based on the good agreement between the measurements in the presence of water and the calculations of our proposed reaction mechanism, we have shown that water in the solvent plays a significant role in the formation of the epoxide ring.

Funder

New Energy and Industrial Technology Development Organization

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP00820G

Reference33 articles.

1. Oxydation ungesättigter Verbindungen mittels organischer Superoxyde

2. Chemo-enzymatic epoxidation of unsaturated plant oils

3. Prilezhaev epoxidation of oleic acid in the presence and absence of ultrasound irradiation

4. Green epoxy synthesized from Perilla frutescens: A study on epoxidation and oxirane cleavage kinetics of high-linolenic oil

5. In Situ exsolved Au nanoparticles from perovskite oxide for efficient epoxidation of styrene

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