Far-red triplet sensitized Z-to-E photoswitching of azobenzene in bioplastics

Author:

Bharmoria Pankaj12ORCID,Ghasemi Shima1,Edhborg Fredrik1ORCID,Losantos Raúl34ORCID,Wang Zhihang1ORCID,Mårtensson Anders1,Morikawa Masa-aki5,Kimizuka Nobuo5ORCID,İşci Ümit6ORCID,Dumoulin Fabienne7ORCID,Albinsson Bo1ORCID,Moth-Poulsen Kasper189ORCID

Affiliation:

1. Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Kemivägen 4, 412 96, Gothenburg, Sweden

2. Department of Chemistry and Molecular Biology, University of Gothenburg, Kemigården 10, Göteborg, 412 96, Gothenburg, Sweden

3. Université de Paris Cité and CNRS, ITODYS, F-75006 Paris, France

4. Universidad de La Rioja, Departamento de Química, Centro de Investigación en Síntesis Química, Madre de Dios, 53, 26006 Logroño, Spain

5. Department of Applied Chemistry, Graduate School of Engineering, Center for Molecular Systems (CMS), Kyushu University 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

6. Gebze Technical University, Chemistry Department, 41400 Gebze Kocaeli, Turkey

7. Acıbadem Mehmet Ali Aydınlar University, Faculty of Engineering and Natural Sciences, Biomedical Engineering Department, Ataşehir, Istanbul, Turkey

8. The Institute of Materials Science of Barcelona, ICMAB-CSIC, Bellaterra, 08193, Barcelona, Spain

9. Catalan Institution for Research & Advanced Studies, ICREA, Pg. Lluís Companys 23, Barcelona, Spain

Abstract

We report the first example of direct far-red endothermic triplet sensitized Z-to-E photoswitching of azobenzene derivative (Azo1) in a condensed phase of a liquid Azo1 co-assembled within a liquid surfactant-protein bioplastic film in air.

Funder

H2020 European Research Council

H2020 Marie Skłodowska-Curie Actions

Japan Society for the Promotion of Science

Energimyndigheten

Göran Gustafssons Stiftelser

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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