Unveiling nanopore-confined crystallization and coordination/de-coordination mechanisms of quinone molecules for ultrahigh-rate and ultralong-cyclability aqueous zinc–organic batteries

Author:

Meng Shuo12,He Ting12,Chen Lu1,Liao Kexuan1,Lu Hang1,Liu Tingting1,Meng Ruijin3,Ma Jie4ORCID,Zhang Chi12ORCID,Yang Jinhu12ORCID

Affiliation:

1. School of Chemical Science and Engineering, Tongji University, Shanghai 200092, P. R. China

2. State Key Laboratory of Cardiovascular Diseases and Medical Innovation Center, Shanghai East Hospital, School of Medicine, Tongji University, 150 Jimo Road, Shanghai 200120, P. R. China

3. Department of Applied Physics, The Hong Kong Polytechnic University, Hunghom, Hong Kong

4. College of Environmental Science and Engineering, Tongji University, Shanghai 200092, P. R. China

Abstract

A fundamental mechanism underlying nanopore-confined crystallization and coordination/de-coordination reactions of quinone molecules has been proposed, enabling highly stable and fast Zn2+ storage for aqueous zinc–organic batteries.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shanghai Municipality

Shanghai Municipal Education Commission

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

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