Dioxygen binding at a four-coordinate cobaltous porphyrin site in a metal–organic framework: structural, EPR, and O2 adsorption analysis
Author:
Affiliation:
1. Department of Chemistry
2. Northwestern University
3. 2145 Sheridan Road, Evanston
4. USA
Abstract
The binding of O2 at a four-coordinate cobaltous porphyrin site within a metal–organic framework is examined through single-crystal X-ray diffraction, EPR spectroscopy, and O2 adsorption measurements.
Funder
Army Research Office
Air Force Office of Scientific Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/QI/C5QI00275C
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