Electrically switchable magnetic exchange in the vibronic model of linear mixed valence triferrocenium complex

Author:

Palii Andrew12345,Tsukerblat Boris6789ORCID,Aldoshin Sergey123,Clemente-Juan Juan M.10111213,Coronado Eugenio10111213ORCID

Affiliation:

1. Institute of Problems of Chemical Physics

2. Chernogolovka

3. Russia

4. Institute of Applied Physics

5. Academy of Sciences of Moldova

6. Department of Chemistry

7. Ben-Gurion University of the Negev

8. Beer-Sheva 84105

9. Israel

10. Instituto de Ciencia Molecular (ICMol)

11. Universidad de Valencia

12. 46980 Paterna

13. Spain

Abstract

A vibronic model for the electric field control of antiferromagnetic exchange is developed for the linear mixed-valence triferrocenium complex Fe(iii)–Fe(ii)–Fe(iii), which is proposed as possible molecular candidate for the implementation of a quantum logic gate.

Funder

European Cooperation in Science and Technology

Ministry of Education and Science of the Russian Federation

Ministerio de Economía y Competitividad

Generalitat Valenciana

Universitat de València

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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