Ion and water transport reasonably involves rotation and pseudorotation: measurement and modeling the temperature dependence of small-angle neutron scattering from aqueous SrI2
Author:
Affiliation:
1. Department of Biochemistry and Molecular Biology
2. Wright State University
3. Dayton
4. USA
5. NIST Center for Neutron Research
6. Chemical Sciences Division
7. National Institute of Standards and Technology
8. Gaithersburg
Abstract
SrI2 ions at 0.8 M in water are present with a structure that can scatter neutrons, and, within experimental uncertainty, the structure does not change between 10 °C and 90 °C, showing an organization that must be reconciled with ionic transport.
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02088E
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1. Measurement of enthalpies and entropies of activation as a function of pairwise distance for the pairwise relative diffusion of SrI2 in water over lengthscales from 6 Å to 40 Å;New Journal of Chemistry;2022
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