Facile synthesis of α-sulfonyl ketoximes from alkenes using sodium sulfinate and NaNO<sub>2</sub> in water-Reference-Cited by-同舟云学术

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Facile synthesis of α-sulfonyl ketoximes from alkenes using sodium sulfinate and NaNO₂ in water

Published:2024 Issue:18 Volume:11 Page:5054-5060
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhang Zhenlei¹^ORCID,Zhu Ning¹,Liu Tianheng¹

Affiliation:

1. School of Chemistry and Material Engineering, Engineering Research Center of Biomass Conversion and Pollution Prevention of Anhui Educational Institutions, Biomass-derived Functional Oligosaccharides Engineering Technology Research Center of Anhui Province, Fuyang Normal University, Fuyang, Anhui, 236037, P. R. China

Abstract

We have developed a new synthesis method for α-sulfonyl ketoximes from pyridine alkenes, sodium sulfinate, and NaNO2 in water. This three-component approach allows the one-step formation of C–N and C–S bonds under mild conditions.

Funder

Fuyang Normal University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO01108B

Reference50 articles.

1. Chemistry of electrochemical oxidative reactions of sulfinate salts

2. Synthesis and applications of sodium sulfinates (RSO2Na): a powerful building block for the synthesis of organosulfur compounds

3. An update on the use of sulfinate derivatives as versatile coupling partners in organic chemistry

4. Sulfination of alcohols with sodium sulfinates promoted by BF3·OEt2: an unexpected access

5. EDA mediated S–N bond coupling of nitroarenes and sodium sulfinate salts

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