Molecular modification of spiro[fluorene-9,9′-xanthene]-based dopant-free hole transporting materials for perovskite solar cells

Author:

Kumar Vinay12,Kumar Deepak12,Chavan Rohit D.3ORCID,Kumar Kodali Phani12ORCID,Yadagiri Bommaramoni12,Ans Muhammad3ORCID,Kruszyńska Joanna3ORCID,Mahapatra Apurba3ORCID,Nawrocki Jan3ORCID,Nikiforow Kostiantyn3,Mrkyvkova Nada45,Siffalovic Peter45ORCID,Yadav Pankaj67,Akin Seckin8,Singh Surya Prakash12ORCID,Prochowicz Daniel3ORCID

Affiliation:

1. Department of Polymer and Functional Material, CSIR-Indian Institute of Chemical Technology (IICT), Uppal Road, Tarnaka, Hyderabad-500007, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

3. Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland

4. Institute of Physics, Slovak Academy of Sciences, Dubravska cesta 9, 84511 Bratislava, Slovakia

5. Center for Advanced Materials and Applications, Slovak Academy of Sciences, Dubravska cesta 9, 84511 Bratislava, Slovakia

6. Department of Solar Energy, School of Energy Technology, Pandit Deendayal Energy University, Gandhinagar-382 007, Gujarat, India

7. Department of Physics, School of Energy Technology, Pandit Deendayal Energy University, Gandhinagar-382 007, Gujarat, India

8. Department of Metallurgical and Materials Engineering, Necmettin Erbakan University, Konya, 42090, Turkey

Abstract

Two spiro-OMeTAD analogues featuring a spiro[fluorene-9,9-xanthene] central core have been designed and applied in PSCs as dopant-free HTLs. The device based on SP-SMe reveals better performance and operational stability than the spiro-OMeTAD-based device.

Funder

Narodowe Centrum Nauki

Agentúra na Podporu Výskumu a Vývoja

Slovenská Akadémia Vied

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

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