Engineered π⋯π interactions favour supramolecular dimers X@[FeL<sub>3</sub>]<sub>2</sub> (X = Cl, Br, I): solid state and solution structure-Reference-Cited by-同舟云学术

Engineered π⋯π interactions favour supramolecular dimers X@[FeL₃]₂ (X = Cl, Br, I): solid state and solution structure

Published:2024 Issue:24 Volume:15 Page:9047-9053
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Risa Arnau¹,Barrios Leoní A.¹²^ORCID,Diego Rosa¹²,Roubeau Olivier³⁴^ORCID,Aleshin Dmitry Y.⁵^ORCID,Nelyubina Yulia⁶⁷^ORCID,Novikov Valentin¹⁷^ORCID,Teat Simon J.⁸^ORCID,Ribas-Ariño Jordi⁹^ORCID,Aromí Guillem¹²^ORCID

Affiliation:

1. Departament de Química Inorgànica i Orgànica, Secció Química Inorgànica, Universitat de Barcelona, Barcelona, Spain

2. Institute of Nanoscience and Nanotechnology of the University of Barcelona (IN2UB), Barcelona, Spain

3. Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, Zaragoza, Spain

4. Departamento de Física de la Materia Condensada, Universidad de Zaragoza, Zaragoza, Spain

5. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia

6. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russia

7. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Acad. Semenov Str. 1, Chernogolovka, 142432, Russia

8. Advanced Light Source, Berkeley Laboratory, 1 Cyclotron Road, Berkeley, California 94720, USA

9. Departament de Química Física, IQTCUB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain

Abstract

The engineered supramolecular recognition of coordination complexes achieved by ligand design is shown in the solid state and in solution via X-ray diffraction and paramagnetic H-NMR spectroscopy.

Funder

Ministerio de Ciencia e Innovación

Institució Catalana de Recerca i Estudis Avançats

Ministry of Science and Higher Education of the Russian Federation

Generalitat de Catalunya

Gobierno de Aragón

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC01365D

Reference44 articles.

1. Perspectives in Supramolecular Chemistry—From Molecular Recognition towards Molecular Information Processing and Self-Organization

2. Combining supramolecular chemistry with biology

3. Multivalency and Cooperativity in Supramolecular Chemistry

4. Artificial Molecular Machines

5. D. W.Johnson and F.Hof , Aromatic Interactions: Frontiers in Knowledge and Application , The Royal Society of Chemistry , 2017