A DFT study to unravel the ligand exchange kinetics and thermodynamics of OsVIII oxo/hydroxido/aqua complexes in aqueous matrices
Author:
Affiliation:
1. Department of Chemistry and Polymer Science
2. Stellenbosch University
3. Western Cape
4. South Africa
Abstract
The OsVIII oxo/hydroxido complexes abundant in mild to relatively concentrated basic aqueous solutions are OsVIIIO4, [OsVIIIO4(OH)]− and two cis-[OsVIIIO4(OH)2]2− species.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00657D
Reference70 articles.
1. Ligand-Assisted Reduction of Osmium Tetroxide with Molecular Hydrogen via a [3+2] Mechanism
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3. Efficient Osmium/Rhenium-Catalyzed Dihydroxylation of Olefins with Hydrogen Peroxide under Acidic Conditions
4. Kinetics of osmium(VIII) catalyzed oxidation of allyl alcohol by potassium bromate in aqueous acidic medium-autocatalysis in catalysis
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1. Experimental Demonstration and Density Functional Theory Mechanistic Analysis of Arene C–H Bond Oxidation and Product Protection by Osmium Tetroxide in a Strongly Basic/Nucleophilic Solvent;The Journal of Organic Chemistry;2022-10-03
2. Kinetic UV–Vis Spectroscopic and DFT Mechanistic Study of the Redox Reaction of [OsVIIIO4(OH)n]n− (n = 1, 2) and Methanol in a Basic Aqueous Matrix;Inorganic Chemistry;2021-01-07
3. A DFT Mechanistic Study of the trans-[OsVIO2(OH)4]2– and [OsVIIIO4(OH)n]n− (n = 1, 2 cis) Comproportionation Proton-Coupled Electron Transfer Reaction;Inorganic Chemistry;2018-07-24
4. A spectroscopic (stopped-flow UV–Vis and 1 H NMR Evans method) and DFT thermodynamic study of the comproportionation reaction of [Os VIII O 4 (OH) n ] n − ( n = 1, 2) and [Os VI O 2 (OH) 4 ] 2−;Inorganica Chimica Acta;2017-01
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