Methyl tunnelling of adsorbed methoxy on alumina catalysts-Reference-Cited by-同舟云学术

Methyl tunnelling of adsorbed methoxy on alumina catalysts

Published:2016 Issue:2 Volume:52 Page:366-369
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Parker Stewart F.¹²³⁴⁵,Sakai Victoria García¹²³⁴,Lennon David⁵⁶²³⁴,Jackson Alice⁷⁸⁹,Johnson Mark R.⁷⁸⁹,Jayasooriya Upali A.¹⁰¹¹¹²¹³⁴

Affiliation:

1. ISIS Facility

2. STFC Rutherford Appleton Laboratory

3. Didcot

4. UK

5. UK Catalysis Hub

6. Research Complex at Harwell

7. Institut Laue-Langevin

8. F – 38042 Grenoble Cedex 9

9. France

10. School of Chemistry

11. Faculty of Science

12. University of East Anglia

13. Norwich

Abstract

We show that the methyl group of the adsorbed methoxy intermediate on industrial grade alumina catalysts undergoes rotational tunnelling, potentially allowing the subtle intermolecular interactions between adsorbed species and catalyst to be probed.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC08223D

Reference8 articles.

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2. H. J. Arpe , Industrial Organic Chemistry, Wiley-VCH, Weinheim, 3rd edn, 2010

3. R. J. Farrauto and C. H.Bartholomew, Fundamentals of Industrial Catalytic Processes, Blackie, London, 1997, p. 60

4. The interaction of alumina with HCl: An infrared spectroscopy, temperature-programmed desorption and inelastic neutron scattering study

5. An infrared and inelastic neutron scattering spectroscopic investigation on the interaction of η-alumina and methanol

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