Thioborates: potential nonlinear optical materials with rich structural chemistry

Author:

Lian Yu-kun12345,Wu Li-Ming12345,Chen Ling12345ORCID

Affiliation:

1. Beijing Key Laboratory of Energy Conversion and Storage Materials

2. College of Chemistry

3. Key Laboratory of Theoretical and Computational Photochemistry

4. Ministry of Education

5. Beijing Normal University

Abstract

This review summarizes thioborates and their structural motifs ranging from zero-dimension to three-dimension. The most commonly observed building units of these examples are planar-triangle BS3 and tetrahedron BS4. Thioborates possess advantages with respect to their structural diversity, optical nonlinearity, laser-induced damage threshold and transparency range, and represent potentially a rich supply of new nonlinear optical materials.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference97 articles.

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2. X. T. Wu and L.Chen, Structure−Property Relationships in Nonlinear Optical Crystals. II. The IR Region, in Struct. Bonding (Berlin), ed. D. M. P. Mingos, Springer, New York, Series edn, 2012, vol. 145

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