N–H cleavage as a route to new pincer complexes of high-valent rhenium-Reference-Cited by-同舟云学术

N–H cleavage as a route to new pincer complexes of high-valent rhenium

Published:2016 Issue:46 Volume:45 Page:18532-18540
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kosanovich Alex J.¹²³⁴,Shih Wei-Chun¹²³⁴,Ramírez-Contreras Rodrigo¹²³⁴,Ozerov Oleg. V.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Texas A&M University

3. College Station

4. USA

Abstract

Rhenium oxo complexes of a new PNN (phosphine-amido-amido) pincer ligand display rotameric isomerism and can be reversibly protonated.

Funder

Division of Human Resource Development

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03640F

Reference38 articles.

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2. Organometallic Pincer Chemistry. In Topics in Organometallic Chemistry, ed. G. van Koten and D. Milstein, Springer, Heidelberg, 2013., vol 40, pp. 1–356

3. K. J. Szabó and O. F.Wendt, Pincer and Pincer-Type Complexes: Applications in Organic Synthesis and Catalysis, John Wiley & Sons, Weinheim, 2014

4. Catalysis Involving Phosphinite-Based Metallacycles

5. Noninnocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes

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