Lanthanoid single-ion magnets with the LnN10 coordination geometry-Reference-Cited by-同舟云学术

Lanthanoid single-ion magnets with the LnN10 coordination geometry

Published:2016 Issue:37 Volume:52 Page:6261-6264
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Jiang Zhong-Xia¹²³⁴⁵,Liu Jun-Liang¹²³⁴⁵^ORCID,Chen Yan-Cong¹²³⁴⁵,Liu Jiang¹²³⁴⁵,Jia Jian-Hua¹²³⁴⁵,Tong Ming-Liang¹²³⁴⁵

Affiliation:

1. MOE Key Lab of Bioinorganic and Synthetic Chemistry

2. School of Chemistry and Chemical Engineering

3. Sun Yat-Sen University

4. Guangzhou 510275

5. P. R. China

Abstract

Two unprecedented single-ion magnets (SIMs) with the homoatomic LnN₁₀ coordination geometry were reported, where the central Ln (Ln = Dy^III or Er^III) ion is interlocked by two pentadentate ligands (N5) affording a low symmetric polyhedron. Studies of the dynamic magnetic behaviours show an effective energy of 79(4) K for [Dy(N5)₂]³⁺ and 59(4) K for [Er(N5)₂]³⁺, respectively.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC01695B

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