Divergent upgrading pathways of sulfones with primary alcohols: nickel-catalyzed α-alkylation under N<sub>2</sub> and metal-free promoted β-olefination in open air-Reference-Cited by-同舟云学术

Divergent upgrading pathways of sulfones with primary alcohols: nickel-catalyzed α-alkylation under N₂ and metal-free promoted β-olefination in open air

Published:2023 Issue:5 Volume:59 Page:615-618
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yu Haiping¹,Fu Kaiyue¹,Yang Guang¹,Liu Mengyu¹,Yang Peng¹²^ORCID,Liu Tao¹

Affiliation:

1. College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan, 250014, P. R. China

2. State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology, Taiyuan, 030024, China

Abstract

Coupling of sulfones and alcohols catalyzed by Ni(OAc)2/P(t-Bu)3 undergoes α-alkylation while β-olefination proceeds in the presence of a base and air.

Funder

China Association for Science and Technology

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC05882K

Reference49 articles.

1. Borrowing Hydrogen in the Activation of Alcohols

2. Hydrogen Autotransfer in the N-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles

3. Advances in Asymmetric Borrowing Hydrogen Catalysis

4. Transition-Metal-Catalyzed Hydrogen-Transfer Annulations: Access to Heterocyclic Scaffolds

5. Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation

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