Regiospecific and site-selective C–H allylation of phenols with vinyldiazo compounds catalyzed by In(iii)-Reference-Cited by-同舟云学术

Regiospecific and site-selective C–H allylation of phenols with vinyldiazo compounds catalyzed by In(iii)

Published:2021 Issue:22 Volume:8 Page:6252-6258
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhao Dan¹,Luo Jingyan¹,Liu Lu¹^ORCID,Liu Yuanyuan¹²^ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China

2. Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, P. R. China

Abstract

An In(OTf)3-catalyzed regiospecific, site-selective, and C–H chemoselective insertion reaction of phenols with vinyldiazoacetates was developed. The reactions of aryl or alkyl substituted vinyldiazoacetates exhibited different selective manners.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO01184G

Reference82 articles.

1. C-H Bond Functionalization in Complex Organic Synthesis

2. If CH Bonds Could Talk: Selective CH Bond Oxidation

3. Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities