Metamorphic meta isomer: carbon dioxide and ketenes are formed via retro-Diels–Alder reactions in the decomposition of meta-benzenediol-Reference-Cited by-同舟云学术

Metamorphic meta isomer: carbon dioxide and ketenes are formed via retro-Diels–Alder reactions in the decomposition of meta-benzenediol

Published:2019 Issue:35 Volume:21 Page:19480-19487
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Gerlach Marius¹²³⁴,Bodi Andras¹²³⁴^ORCID,Hemberger Patrick¹²³⁴^ORCID

Affiliation:

1. Laboratory for Synchrotron Radiation and Femtochemistry

2. Paul Scherrer Institute

3. CH-5234 Villigen PSI

4. Switzerland

Abstract

Deoxygenation of the lignin model compound resorcinol was investigated using VUV synchrotron radiation: Formation of two reactive ketenes and decarboxylation are the dominating pathways, much different from the other two benzenediol isomers.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Bundesamt für Energie

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP03519B

Reference60 articles.

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