Synthesis of regioblock copolythiophene by Negishi catalyst-transfer polycondensation using tBu2Zn·2LiCl

Author:

Goto Eisuke12345,Ochiai Yuto12345,Lo Chen-Tsyr12345,Koganezawa Tomoyuki675,Ueda Mitsuru12345,Higashihara Tomoya12345ORCID

Affiliation:

1. Department of Organic Materials Science

2. Graduate School of Organic Materials Science

3. Yamagata University

4. Yonezawa

5. Japan

6. Japan Synchrotron Radiation Research Institute (JASRI)

7. Hyogo 679-5198

Abstract

Regioblock copolythiohenes consisting of head-to-tail poly(3-hexylthiophene) (HT-P3HT) and head-to-head/tail-to-tail P3HT (HHTT-P3HT) segments could be synthesized by Negishi catalyst-transfer polycondensation (NCTP) using tBu2Zn·2LiCl.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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