Highly syndioselective coordination (co)polymerization of isopropenylstyrene-Reference-Cited by-同舟云学术

Highly syndioselective coordination (co)polymerization of isopropenylstyrene

Published:2018 Issue:35 Volume:9 Page:4476-4482
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Zhang Zhen¹²³⁴⁵,Dou Yanli⁶⁷⁸⁹⁵,Li Shihui¹²³⁴⁵^ORCID,Cui Dongmei¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Polymer Physics and Chemistry

2. Changchun Institute of Applied Chemistry

3. Chinese Academy of Sciences

4. Changchun 130022

5. China

6. Key Laboratory of Automobile Materials of Ministry of Education

7. Department of Materials Science and Engineering

8. Jilin University

9. Changchun

Abstract

Coordination (co)polymerization of para-isopropenylstyrene (pIPSt) and meta-isopropenylstyrene (mIPSt), initiated by scandium (Sc) based catalysts, afforded new type of products, bearing pendant isopropenyl groups with perfect syndiotacity (rrrr > 99%).

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2018/PY/C8PY00625C

Reference36 articles.

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3. Scandium Half-Metallocene-Catalyzed Syndiospecific Styrene Polymerization and Styrene−Ethylene Copolymerization: Unprecedented Incorporation of Syndiotactic Styrene−Styrene Sequences in Styrene−Ethylene Copolymers