Structure–activity correlation in aerobic cyclohexene oxidation and peroxide decomposition over CoxFe3−xO4 spinel oxides

Author:

Büker Julia1,Angel Steven2,Salamon Soma3ORCID,Landers Joachim3ORCID,Falk Tobias1,Wende Heiko3ORCID,Wiggers Hartmut2,Schulz Christof2,Muhler Martin14ORCID,Peng Baoxiang14ORCID

Affiliation:

1. Laboratory of Industrial Chemistry, Ruhr University Bochum, 44780 Bochum, Germany

2. IVG Institute for Combustion and Gas Dynamics – Reactive Fluids and CENIDE Center for Nanointegration, University of Duisburg-Essen, 47057 Duisburg, Germany

3. Faculty of Physics, University of Duisburg-Essen, 47057 Duisburg, Germany

4. Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, Germany

Abstract

Aerobic cyclohexene oxidation and peroxide decomposition in the liquid phase were performed over a series of CoxFe3−xO4 spinel catalysts exhibiting a volcano plot for the catalytic activity with a maximum at x = 1.

Funder

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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