Reduction of CO2 with H2S in a simulated deep-sea hydrothermal vent system

Author:

He Runtian12345,Hu Baoyun6785,Zhong Heng12345,Jin Fangming12345ORCID,Fan Junjie6785,Hu Yun Hang9101112ORCID,Jing Zhenzi6785ORCID

Affiliation:

1. School of Environmental Science and Engineering

2. State Key Lab of Metal Matrix Composites

3. Shanghai Jiao Tong University

4. Shanghai 200240

5. P. R. China

6. School of Materials Science & Engineering

7. Tongji University

8. Shanghai 201804

9. Department of Materials Science and Engineering

10. Michigan Technological University

11. Houghton

12. USA

Abstract

CO2 can be reduced to organic molecules, such as formic and acetic acids in a yield of approximately 67% with metal sulfides catalysts, using H2S as a reductant and with SxOy2− as oxidative products in a simulated hydrothermal vent system. These results are significant for understanding abiotic organic synthesis from dissolved CO2 in deep sea hydrothermal vents.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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