Carbene-catalyzed enal γ-carbon addition to α-ketophosphonates for enantioselective access to bioactive 2-pyranylphosphonates-Reference-Cited by-同舟云学术

Carbene-catalyzed enal γ-carbon addition to α-ketophosphonates for enantioselective access to bioactive 2-pyranylphosphonates

Published:2018 Issue:47 Volume:54 Page:6040-6043
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sun Jun¹²³⁴⁵,He Fangcheng¹²³⁴⁵,Wang Zhongyao¹²³⁴⁵,Pan Dingwu¹²³⁴⁵,Zheng Pengcheng¹²³⁴⁵^ORCID,Mou Chengli⁶⁷⁴⁵^ORCID,Jin Zhichao¹²³⁴⁵^ORCID,Chi Yonggui Robin¹²³⁴⁵

Affiliation:

1. Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering

2. Key Laboratory of Green Pesticide and Agricultural Bioengineering Ministry of Education

3. Guizhou University

4. Guiyang 550025

5. China

6. School of Pharmacy

7. Guiyang College of Traditional Chinese Medicine

Abstract

A carbene-catalyzed [4+2] reaction of enals and α-ketophosphonates is developed to afford chiral 2-pyranylphosphonates with potential use in plant protection.

Funder

Nanyang Technological University

National Natural Science Foundation of China

Guizhou University

National Research Foundation Singapore

Ministry of Education - Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC03017K

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