Through-space hopping transport in an iodine-doped perylene-based metal–organic framework-Reference-Cited by-同舟云学术

Through-space hopping transport in an iodine-doped perylene-based metal–organic framework

Published:2022 Issue:9 Volume:7 Page:1065-1072
ISSN:2058-9689
Container-title:Molecular Systems Design & Engineering
language:en
Short-container-title:Mol. Syst. Des. Eng.

Author:

Valente Gonçalo¹^ORCID,Esteve-Rochina María²^ORCID,Paracana Ana³,Rodríguez-Diéguez Antonio⁴^ORCID,Choquesillo-Lazarte Duane⁵^ORCID,Ortí Enrique²^ORCID,Calbo Joaquín²^ORCID,Ilkaeva Marina¹^ORCID,Mafra Luís¹^ORCID,Hernández-Rodríguez Miguel A.³^ORCID,Rocha João¹^ORCID,Alves Helena²^ORCID,Souto Manuel¹^ORCID

Affiliation:

1. Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Aveiro, 3810-393, Portugal

2. Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/Catedrático José Beltrán, 2, 46980 Paterna, Spain

3. Department of Physics, CICECO-Aveiro Institute of Materials, University of Aveiro, Aveiro, 3810-393, Portugal

4. Department of Inorganic Chemistry, University Granada, 18071, Granada, Spain

5. Laboratorio de Estudios Cristalográficos, IACT, CSIC-Universidad Granada, Granada, 18100, Spain

Abstract

We report the electrical conductivity enhancement of a perylene-based MOF upon partial ligand oxidation. The conductivity enhancement is rationalised by quantum-chemical calculations, supporting a through-space hopping transport.

Funder

Centro de Investigação em Materiais Cerâmicos e Compósitos

Ministerio de Ciencia e Innovación

Fundação para a Ciência e a Tecnologia

Generalitat Valenciana

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Industrial and Manufacturing Engineering,Process Chemistry and Technology,Energy Engineering and Power Technology,Biomedical Engineering,Chemical Engineering (miscellaneous),Chemistry (miscellaneous)

Link

http://pubs.rsc.org/en/content/articlepdf/2022/ME/D2ME00108J

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