Merohedral icosahedral M48 (M = CoII, NiII) cage clusters supported by thiacalix[4]arene

Author:

Geng Dantong12345,Han Xu12345,Bi Yanfeng12345ORCID,Qin Yucai12345,Li Qiang12345,Huang Liangliang12345ORCID,Zhou Kun12345ORCID,Song Lijuan12345ORCID,Zheng Zhiping12345ORCID

Affiliation:

1. College of Chemistry

2. Chemical Engineering and Environmental Engineering

3. Liaoning Shihua University

4. Fushun 113001

5. P. R. China

Abstract

Highest nuclearity M48 (M = CoII or NiII) cage clusters have been constructed by [12+18] condensation of twelve M4-p-tert-butylthiacalix[4]arene second building units (as vertices) and eighteen asymmetric 5-(1H-tetrazol-1-yl)isophthalate ligands (as faces), showing a merohedral icosahedron-type framework.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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