Designed synthesis of size-tunable Ag2S nanoclusters via distinguishable C–S bond cleavage reaction of alkyl- and aryl-thiolates-Reference-Cited by-同舟云学术

Designed synthesis of size-tunable Ag2S nanoclusters via distinguishable C–S bond cleavage reaction of alkyl- and aryl-thiolates

Published:2015 Issue:9 Volume:44 Page:3963-3966
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chen Hang-Qing¹²³⁴⁵,He Xin¹²³⁴⁵,Guo Hui¹²³⁴⁵,Fu Nan-Yan²⁶⁷⁵,Zhao Liang¹²³⁴⁵

Affiliation:

1. Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education)

2. Department of Chemistry

3. Tsinghua University

4. Beijing 100084

5. China

6. Fuzhou University

7. Fuzhou 350108

Abstract

We report herein the synthesis of two aryl- and alkyl-thiolates silver clusters. The two complexes exhibited biased C–S bond cleavage rates upon removing protective ligands and applied for fabricating silver sulfide nanoclusters with variable sizes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT04021J

Reference27 articles.

1. Preparation and characterization of polymer thin films containing silver and silver sulfide nanoparticles

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4. Infrared Emitting and Photoconducting Colloidal Silver Chalcogenide Nanocrystal Quantum Dots from a Silylamide-Promoted Synthesis

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