Restricted rotation of an Fe(CO)2(PL3)-subunit in [FeFe]-hydrogenase active site mimics by intramolecular ligation-Reference-Cited by-同舟云学术

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Restricted rotation of an Fe(CO)2(PL3)-subunit in [FeFe]-hydrogenase active site mimics by intramolecular ligation

Published:2019 Issue:18 Volume:48 Page:5933-5939
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pullen Sonja¹²³⁴⁵^ORCID,Maji Somnath¹²³⁴⁵,Stein Matthias⁶⁷⁸^ORCID,Ott Sascha¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Ångström Laboratory

3. Uppsala University

4. 75120 Uppsala

5. Sweden

6. Max Planck Institute for Dynamics of Complex Technical Systems

7. 39106 Magdeburg

8. Germany

Abstract

Terminal ligand fixation by covalent linkage to the bridging bdt ligand hinders ligand rotations.

Funder

Vetenskapsrådet

Knut och Alice Wallenbergs Stiftelse

Energimyndigheten

Max-Planck-Gesellschaft

European Cooperation in Science and Technology

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT05148H

Reference41 articles.

1. Hydrogenases: Hydrogen-Activating Enzymes

2. X-ray Crystal Structure of the Fe-Only Hydrogenase (CpI) from Clostridium pasteurianum to 1.8 Angstrom Resolution

3. Investigations on the Role of Proton-Coupled Electron Transfer in Hydrogen Activation by [FeFe]-Hydrogenase

4. Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases

5. Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory

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1. Mononuclear manganese complexes as hydrogen evolving catalysts;Frontiers in Chemistry;2022-10-07

2. Toward Diiron Dithiolato Biomimetics with Rotated Conformation of the [FeFe]‐Hydrogenase Active Site: A DFT Case Study on Electron‐Rich, Isocyanide‐Based Scaffolds;European Journal of Inorganic Chemistry;2022-03-30

3. Mechanism of Diiron Hydrogenase Complexes Controlled by Nature of Bridging Dithiolate Ligand;ChemistryOpen;2022-01

4. Catalytic systems mimicking the [FeFe]-hydrogenase active site for visible-light-driven hydrogen production;Coordination Chemistry Reviews;2021-12

5. Switching Site Reactivity in Hydrogenase Model Systems by Introducing a Pendant Amine Ligand;ACS Omega;2021-02-02

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