Synthesis of (E)-1,4-disilsesquioxylsubstituted but-1-en-3-ynes via platinum-catalyzed dimerization of ethynylsiloxysilsesquioxanes-Reference-Cited by-同舟云学术

Synthesis of (E)-1,4-disilsesquioxylsubstituted but-1-en-3-ynes via platinum-catalyzed dimerization of ethynylsiloxysilsesquioxanes

Published:2019 Issue:8 Volume:48 Page:2657-2663
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Żak Patrycja¹²³⁴⁵^ORCID,Bołt Małgorzata¹²³⁴⁵,Dudziec Beata¹²³⁴⁵^ORCID,Kubicki Maciej¹²³⁴⁵^ORCID

Affiliation:

1. Department of Organometallic Chemistry

2. Faculty of Chemistry

3. Adam Mickiewicz University in Poznan

4. 61-614 Poznan

5. Poland

Abstract

The [Pt(IPr*^Ph)(dvtms)] complex efficiently catalyzes the E-selective dimerization of ethynylsiloxysilsesquioxanes leading to a novel class of silsesquioxane derivatives, resembling their dumbbell-shaped analogues.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT05142A

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