Synthesis of (E)-1,4-disilsesquioxylsubstituted but-1-en-3-ynes via platinum-catalyzed dimerization of ethynylsiloxysilsesquioxanes
Author:
Affiliation:
1. Department of Organometallic Chemistry
2. Faculty of Chemistry
3. Adam Mickiewicz University in Poznan
4. 61-614 Poznan
5. Poland
Abstract
The [Pt(IPr*Ph)(dvtms)] complex efficiently catalyzes the E-selective dimerization of ethynylsiloxysilsesquioxanes leading to a novel class of silsesquioxane derivatives, resembling their dumbbell-shaped analogues.
Funder
Narodowe Centrum Nauki
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT05142A
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3. Recent advances in transition-metal-catalyzed synthesis of conjugated enynes
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5. The Dehydro-Diels−Alder Reaction
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