Synthesis, characterization and catalytic epoxidation properties of a new tellurotungstate(iv)-supported rhenium carbonyl derivative
Author:
Affiliation:
1. Henan Key Laboratory of Polyoxometalate Chemistry
2. Institute of Molecular and Crystal Engineering
3. College of Chemistry and Chemical Engineering
4. Henan University
5. Kaifeng
Abstract
We synthesized a new tellurotungstate(iv)-supported rhenium carbonyl derivative, Na2H2[(CH3)4N]6[Te2W20O70{Re(CO)3}2]·20H2O (1). Additionally, compound 1 showed excellent catalytic activity in the selective epoxidation of alkenes under comparatively mild reaction conditions.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04195D
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