A cobalt–nitrosyl complex with a hindered hydrotris(pyrazolyl)borate coligand: detailed electronic structure, and reactivity towards dioxygen-Reference-Cited by-同舟云学术

A cobalt–nitrosyl complex with a hindered hydrotris(pyrazolyl)borate coligand: detailed electronic structure, and reactivity towards dioxygen

Published:2017 Issue:39 Volume:46 Page:13273-13289
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fujisawa Kiyoshi¹²³⁴,Soma Shoko¹²³⁴,Kurihara Haruka¹²³⁴,Dong Hai T.⁵⁶⁷⁸,Bilodeau Max⁵⁶⁷⁸,Lehnert Nicolai⁵⁶⁷⁸^ORCID

Affiliation:

1. Department of Chemistry

2. Ibaraki University

3. Mito 310-8512

4. Japan

5. Department of Chemistry and Department of Biophysics

6. University of Michigan

7. Ann Arbor

8. USA

Abstract

The cobalt–nitrosyl complex [Co(NO)(L3)] is supported by a highly hindered tridentate nitrogen ligand, hydrotris(3-tertiary butyl-5-isopropyl-1-pyrazolyl)borate (denoted as L3⁻), and shows a linear Co–N–O unit.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01565H

Reference94 articles.

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