Copper-catalyzed syn-hydroformylation of alkynes with silanes and N,N-dimethylformamide dimethylacetal

Author:

Huai Menglin1,Chen Long1,Dong Wei1,Wang Weijie1,Qin Zhen1,Dai Kaifeng1,Li Yuan1,Zhang Xiulian1,Tao Chuanzhou12ORCID

Affiliation:

1. School of Environmental and Chemical Engineering, Jiangsu Ocean University, Lianyungang 222005, China

2. Jiangsu Province Engineering Research Center of Visible Light Catalytic Materials, Lianyungang Technical College, Lianyungang 222000, China

Abstract

A copper-catalyzed syn-hydrocarbonization of internal alkynes with N,N-dimethylformamide dimethylacetal and silanes has been disclosed that offers an efficient and expedient access to (E)-α,β-unsaturated aldehydes.

Publisher

Royal Society of Chemistry (RSC)

Reference68 articles.

1. A.Börner and R.Franke , Hydroformylation: fundamentals, processes, and application in organic synthesis , Wiley-VCH , Weinheim , 2016

2. M.Taddei and A.Mann , Hydroformylation for organic synthesis in topics in current chemistry , Springer , Berlin , 2013 , vol. 342

3. P. W. N. M.Leeuwen and C.van Claver , Rhodium catalyzed hydroformylation , Kluwer Academic Publishers , New York , 2005

4. Applied Hydroformylation

5. E. F.Glorius , in science of synthesis , ed. R. Bruckner , Georg Thieme , Stuttgart , 2007 , vol. 25 , p. 733

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