Hydrogenation of 3-hydroxypropanal into 1,3-propanediol over bimetallic Ru

Hydrogenation of 3-hydroxypropanal into 1,3-propanediol over bimetallic Ru–Ni catalyst

Published:2017 Issue:51 Volume:7 Page:32027-32037
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Li Li-Jun¹²³⁴,Yi Wen-Jun¹²³⁴,Liu Tian-Wei¹²³⁴,Huang Chen¹²³⁴,Chao Zi-Sheng¹²³⁴⁵^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Hunan University

3. Changsha

4. China

5. College of Materials Science and Engineering

Abstract

The introduction of Ru onto the Ni/SiO₂ catalyst promoted not only the reduction of Ni²⁺ to Ni⁰ but also the generation of active hydrogen species and thus increased the 1,3-PDO yield.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA01184A

Reference51 articles.

1. A review: Conversion of bioglycerol into 1,3-propanediol via biological and chemical method

2. Selective conversion of glycerol to 1,3-propanediol using Pt-sulfated zirconia

3. Selective deoxygenation of sugar polyols to α,ω-diols and other oxygen content reduced materials—a new challenge to homogeneous ionic hydrogenation and hydrogenolysis catalysis

4. Catalytic performance of Rh/SiO2 in glycerol reaction under hydrogen

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