Correlations between structure, microstructure and ionic conductivity in (Gd,Sm)-doped ceria

Author:

Artini Cristina12ORCID,Viviani Massimo3ORCID,Presto Sabrina3ORCID,Massardo Sara1,Carnasciali Maria Maddalena14,Gigli Lara5ORCID,Pani Marcella16

Affiliation:

1. DCCI, Department of Chemistry and Industrial Chemistry, University of Genova, Via Dodecaneso 31, 16146 Genova, Italy

2. Institute of Condensed Matter Chemistry and Technologies for Energy, National Research Council, CNR-ICMATE, Via De Marini 6, 16149 Genova, Italy

3. Institute of Condensed Matter Chemistry and Technologies for Energy, National Research Council, CNR-ICMATE, c/o DICCA-UNIGE, Via all’Opera Pia 15, 16145 Genova, Italy

4. INSTM, Genova Research Unit, Via Dodecaneso 31, 16146 Genova, Italy

5. Elettra-Sincrotrone Trieste S.C.p.A., ss 14, km 163.5, 34149 Basovizza, Trieste, Italy

6. CNR-SPIN Genova, Corso Perrone 24, 16152 Genova, Italy

Abstract

In (Gd,Sm)-doped ceria, currently studied as the electrolyte in solid oxide cells, the range of ceria-based solid solution is larger than in singly-doped ceria, and a lower activation energy to ionic conduction occurs above a threshold temperature.

Funder

Compagnia di San Paolo

Elettra-Sincrotrone Trieste

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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