Selective synthesis of trisubstituted pyrroles through the reactions of alkynyl Fischer carbene complexes with oxazolones-Reference-Cited by-同舟云学术

Selective synthesis of trisubstituted pyrroles through the reactions of alkynyl Fischer carbene complexes with oxazolones

Published:2020 Issue:3 Volume:18 Page:538-550
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

López Julio¹²³⁴^ORCID,Velazco-Cabral Iván¹²³⁴^ORCID,Rodríguez-deLeón Eloy¹²³⁴^ORCID,Villegas Gómez Clarisa¹²³⁴^ORCID,Delgado Francisco⁵⁶⁷⁴^ORCID,Tamariz Joaquín⁵⁶⁷⁴^ORCID,Arrieta Ana⁸⁹¹⁰¹¹⁹^ORCID,Cossío Fernando P.⁸⁹¹⁰¹¹⁹^ORCID,Vázquez Miguel A.¹²³⁴^ORCID

Affiliation:

1. Departament of Chemistry

2. University of Guanajuato

3. 36050 Guanajuato, Gto

4. Mexico

5. Departament of Organic Chemistry

6. National School of Biological Sciences-Instituto Politécnico Nacional

7. Ciudad de Mexico

8. Departament of Organic Chemistry I and Centro de Innovación en Química Avanzada (ORFEO-CINQA). Universidad del País Vasco/Euskal Herriko Unibertsitatea (UPV/EHU)

9. 20018 San Sebastian/Donostia

10. Spain

11. Donostia International Physics Center (DIPC)

Abstract

The unexpected reactivity of fluorinated oxazolones with alkynyl Fischer carbenes is reported. The loss of the –CF₃ and a cascade process involving nucleophilic additions were observed.

Funder

Consejo Nacional de Ciencia y Tecnología

Secretaría de Investigación y Posgrado, Instituto Politécnico Nacional

Ministerio de Ciencia, Innovación y Universidades

European Regional Development Fund

Eusko Jaurlaritza

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/C9OB02411E