Small molecule activation with divalent samarium triflate: a synergistic effort to cleave O2-Reference-Cited by-同舟云学术

Small molecule activation with divalent samarium triflate: a synergistic effort to cleave O2

Published:2018 Issue:28 Volume:47 Page:9226-9230
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Xémard Mathieu¹²³⁴⁵,Cordier Marie¹²³⁴⁵,Louyriac Elisa⁶⁷⁸⁹¹⁰,Maron Laurent⁶⁷⁸⁹¹⁰,Clavaguéra Carine¹¹¹²¹³¹⁴¹⁵^ORCID,Nocton Grégory¹²³⁴⁵^ORCID

Affiliation:

1. LCM

2. CNRS

3. Ecole polytechnique

4. Route de Saclay

5. 91128 Palaiseau Cedex

6. LPCNO

7. UMR 5215

8. Université de Toulouse-CNRS

9. INSA

10. UPS

11. Laboratoire de Chimie Physique

12. CNRS-Université Paris-Sud

13. Université Paris-Saclay

14. 91405 Orsay Cedex

15. France

Abstract

The reaction of divalent samarium triflate with O₂ leads to the entire reductive cleavage of O₂, highlighting a synergistic effort since four electrons, and therefore four samarium centers, are necessary.

Funder

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Direction Générale de l’Armement

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02196A

Reference47 articles.

1. Dinitrogen Cleavage by Three-Coordinate Molybdenum(III) Complexes: Mechanistic and Structural Data1

2. In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co 2+

4. Dinitrogen Reduction and CH Activation by the Divalent Organoneodymium Complex [(C5H2tBu3)2Nd(μ-I)K([18]crown-6)]

5. Twenty five years of organic chemistry with diiodosamarium

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