Neptunium(iv)-hydroxamate complexes: their speciation, and kinetics and mechanism of hydrolysis-Reference-Cited by-同舟云学术

Neptunium(iv)-hydroxamate complexes: their speciation, and kinetics and mechanism of hydrolysis

Published:2019 Issue:2 Volume:48 Page:673-687
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Edwards S.¹²³⁴,Andrieux F.¹²³⁴,Boxall C.¹²³⁴^ORCID,Sarsfield M. J.⁵⁶⁷⁴,Taylor R. J.⁵⁶⁷⁴,Woodhead D.⁵⁶⁷⁴

Affiliation:

1. Engineering Department

2. Lancaster University

3. Lancaster

4. UK

5. National Nuclear Laboratory

6. Central Laboratory

7. Sellafield

Abstract

First time determination of rate parameters for hydrolysis of mono- and bis-acetohydroxamatoneptunium(iv) complexes under conditions relevant to nuclear reprocessing.

Funder

Engineering and Physical Sciences Research Council

Lloyd's Register Educational Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT02194E

Reference53 articles.

1. P. D. Wilson , The Nuclear Fuel Cycle: From Ore to Wastes , Oxford University Press , 1996

2. Progress towards the Full Recovery of Neptunium in an Advanced PUREX Process

3. The Hydrolysis of Hydroxamic Acid Complexants in the Presence of Non-oxidizing Metal Ions 1: Ferric Ions

4. The Hydrolysis of Hydroxamic Acid Complexants in the Presence of Non-Oxidizing Metal Ions 2: Neptunium (IV) Ions

5. The applications of formo- and aceto-hydroxamic acids in nuclear fuel reprocessing

Cited by 14 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Experimental testing and process simulation of flowsheets for the co-separation of uranium and plutonium using acetohydroxamic acid as a complexing agent;Progress in Nuclear Energy;2024-11

2. Effect of branching in the alkyl chain of diglycolamide on the sequestration of tetravalent actinides: solvent extraction and theoretical studies;Dalton Transactions;2024

3. The development of future options for aqueous recycling of spent nuclear fuels;Progress in Nuclear Energy;2023-10

4. Highly Efficient Pertraction of Tetravalent Neptunium Ions Across a Flat Sheet Supported Liquid Membrane Containing Two Different Aza-Crown Ether-Based Multiple Diglycolamide Ligands;Solvent Extraction and Ion Exchange;2023-01-25

5. Sequestration of Np4+ and NpO22+ ions by using diglycolamide-functionalized azacrown ethers in C8mim·NTf2 ionic liquid: Extraction, spectroscopic, electrochemical and DFT studies;Journal of Molecular Liquids;2023-01