Thermodynamic description of Tc(iv) solubility and hydrolysis in dilute to concentrated NaCl, MgCl2 and CaCl2 solutions-Reference-Cited by-同舟云学术

Thermodynamic description of Tc(iv) solubility and hydrolysis in dilute to concentrated NaCl, MgCl2 and CaCl2 solutions

Published:2016 Issue:21 Volume:45 Page:8916-8936
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yalçıntaş Ezgi¹²³⁴,Gaona Xavier¹²³⁴,Altmaier Marcus¹²³⁴,Dardenne Kathy¹²³⁴,Polly Robert¹²³⁴,Geckeis Horst¹²³⁴

Affiliation:

1. Institute for Nuclear Waste Disposal

2. Karlsruhe Institute of Technology

3. 76021 Karlsruhe

4. Germany

Abstract

This work represents a systematic investigation of Tc(iv) solubility, hydrolysis and speciation in dilute to concentrated NaCl, MgCl₂ and CaCl₂ systems, and comprehensive thermodynamic and activity models for these systems using both SIT and Pitzer approaches.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00973E

Reference45 articles.

1. J. A. Rard , M. H.Rand, G.Anderegg and H.Wanner, Chemical thermodynamics of technetium, Elsevier, North-Holland, Amsterdam, 1999

2. Radionuclide behaviour in the near-field of a geological repository for spent nuclear fuel

3. E. Wieland and L. R.Van Loon, Cementitious Near-Field Sorption Data Base for Performance Assessment of an ILW Repository in Opalinus Clay, PSI-Bericht 03-06, Nuclear Energy and Safety Research Department Laboratory for Waste Management, 2006

4. Long-term cement corrosion in chloride-rich solutions relevant to radioactive waste disposal in rock salt – Leaching experiments and thermodynamic simulations

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