The effect of remote substitution on the formation of preferential isomers of cobalt(iii)-tetrazolate complexes by microwave assisted cycloaddition

Author:

Saha Manideepa1234,Nasani Rajendar1234,Das Mriganka1234,Mobin Shaikh M.1234,Pathak Biswarup1234,Mukhopadhyay Suman1234

Affiliation:

1. Department of Chemistry

2. School of Basic Sciences

3. Indian Institute of Technology Indore

4. Indore 452017, India

Abstract

Cycloaddition of cis-[Co(N3)2(en)2]NO31 or trans-[Co(N3)2(en)2]ClO41a with organonitriles affords cis/trans cobalt bis-tetrazolate complexes, depending upon ligand substitution, solvent molecules and counteranions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference39 articles.

1. Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials

2. Other Five-membered Rings with Three or more Heteroatoms, and their Fused Carbocyclic Derivatives , in Comprehensive Heterocyclic Chemistry III , ed. V. A. Ostrovskii , G. I. Koldobskii , R. E. Trifonov , A. R. Katritzky , C. A. Ramsden , E. F. V. Scriven and R. J. K. Taylor , Elsevier , Oxford , 2008 , vol. 6 , pp. 257–423

3. Metal derivatives of tetrazoles

4. Metalloantibiotics: Synthesis and Antibacterial Activity of Cobalt(II), Copper(II), Nickel(II) and Zinc(II) Complexes of Kefzol

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