Anion-induced ferroelectric polarization in a luminescent metal–organic cage compound-Reference-Cited by-同舟云学术

Anion-induced ferroelectric polarization in a luminescent metal–organic cage compound

Published:2017 Issue:40 Volume:5 Page:10624-10629
ISSN:2050-7526
Container-title:J. Mater. Chem. C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Yadav Ashok¹²³⁴^ORCID,Srivastava Anant Kumar¹²³⁴^ORCID,Kulkarni Priyangi⁵⁶⁴,Divya Pillutla⁵⁶⁴,Steiner Alexander¹⁷⁸⁹^ORCID,Praveenkumar B.⁵⁶⁴,Boomishankar Ramamoorthy¹²³⁴¹⁰^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Science Education and Research (IISER)

3. Pune – 411008

4. India

5. Armament Research and Development Establishment

6. Pune – 411021

7. University of Liverpool

8. Liverpool – L69 7ZD

9. UK

10. Centre for Energy Science

Abstract

A cage assembly consisting of an axially symmetric nonpolar octahedral [Zn₆L₈] core exhibits an interesting multifunctional luminescence and ferroelectric order at room temperature. The ferroelectric response originates from the toggling of nitrate anions and solvate molecules found in pockets between the cages.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/TC/C7TC03375C

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