<i>N</i>-(2-(Diphenylphosphino)ethyl)-2-alkyl-5,6,7,8-tetrahydro-quinolin-8-amines iron(<scp>ii</scp>) complexes: structural diversity and the ring opening polymerization of ε-caprolactone-Reference-Cited by-同舟云学术

N-(2-(Diphenylphosphino)ethyl)-2-alkyl-5,6,7,8-tetrahydro-quinolin-8-amines iron(ii) complexes: structural diversity and the ring opening polymerization of ε-caprolactone

Published:2023 Issue:43 Volume:13 Page:29866-29878
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Wang Yun¹²³,Zhang Wenjuan¹²^ORCID,Wang Xing²³,Zuo Weiwei¹^ORCID,Xue Xiaopan²,Ma Yanping³^ORCID,Sun Wen-Hua³^ORCID

Affiliation:

1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China

2. Beijing Key Laboratory of Clothing Materials R&D and Assessment, Beijing Engineering Research Center of Textile Nanofiber, School of Materials Science and Engineering, Beijing Institute of Fashion Technology, Beijing 100029, China

3. Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Abstract

A series of 2-alkylated N-(2-(diphenylphosphino)ethyl)-5,6,7,8-tetrahydro-quinolin-8-amines-iron(ii), activated with LiCH2SiMe3, efficiently initiated the ROP of ε-caprolactone with TOF up to 8.8 × 103 h−1, producing PCL within 9.21–24.3 × 104 g mol−1.

Funder

National Natural Science Foundation of China

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials

Donghua University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/RA/D3RA05867K

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